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Caesium Aquo-chlor-ruthenate, Cs2Ru(OH2)Cl5

Caesium Aquo-chlor-ruthenate, Cs2Ru(OH2)Cl5, is an interesting salt inasmuch as it is isomeric with the first chlor-ruthenite to be discovered, namely, Cs2RuCl5.H2O (vide supra). It is obtained as a buff precipitate on adding alcohol to the blue filtrate from electrically reduced solutions of ruthenium trichloride and caesium chloride. On crystallisation, rose-coloured prisms are obtained. These are soluble in water, and may be recrystallised unchanged from aqueous hydrochloric acid.

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