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Atomistry » Ruthenium » Chemical Properties » Potassium Ruthenocyanide | ||
Atomistry » Ruthenium » Chemical Properties » Potassium Ruthenocyanide » |
Potassium Ruthenocyanide, K4Ru(CN)6
Potassium Ruthenocyanide, K4Ru(CN)6.3H2O, is obtained by heating to the point of fusion ammonium chlor-ruthenate with a slight excess of potassium cyanide for ten to fifteen minutes. Extraction of the melt with boiling water and subsequent evaporation yields crystals of potassium ruthenocyanide.
Howe has prepared the salt in a variety of ways, the three yielding the best results were as follows:
Ferrous sulphate yields, with potassium ruthenocyanide, a pale blue precipitate which gradually oxidises to the purple one on standing, but instantly on addition of bromine. With hydrochloric acid hydrogen cyanide is evolved on warming, . and after a time a deep violet-blue precipitate of ruthenium cyanide with a little potassium cyanide is obtained. Chlorine colours the solution brownish yellow, possibly in consequence of the formation of a ruthenicyanide, although no crystalline salt can be isolated from it. |
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